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An Advanced Ni–Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation

Ming Gong, Yanguang Li, Hailiang Wang, Yongye Liang, Justin Z. Wu, Jigang Zhou, Jian Wang, Tom Regier, Fei Wei, Hongjie Dai

Journal of the American Chemical Society · 2013 · 2,852 citations

Abstract

Highly active, durable, and cost-effective electrocatalysts for water oxidation to evolve oxygen gas hold a key to a range of renewable energy solutions, including water-splitting and rechargeable metal-air batteries. Here, we report the synthesis of ultrathin nickel-iron layered double hydroxide (NiFe-LDH) nanoplates on mildly oxidized multiwalled carbon nanotubes (CNTs). Incorporation of Fe into the nickel hydroxide induced the formation of NiFe-LDH. The crystalline NiFe-LDH phase in nanoplate form is found to be highly active for oxygen evolution reaction in alkaline solutions. For NiFe-LDH grown on a network of CNTs, the resulting NiFe-LDH/CNT complex exhibits higher electrocatalytic activity and stability for oxygen evolution than commercial precious metal Ir catalysts.

Cite this paper

Gong, M., Li, Y., Wang, H., Liang, Y., Wu, J. Z., Zhou, J., Wang, J., Regier, T., Wei, F., & Dai, H. (2013). An advanced Ni–Fe layered double hydroxide electrocatalyst for water oxidation. Journal of the American Chemical Society, 135(23), 8452–8455. https://doi.org/10.1021/ja4027715

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