Effects of F- Doping on the Photocatalytic Activity and Microstructures of Nanocrystalline TiO2 Powders

Abstract

A novel and simple method for preparing highly photoactive nanocrystalline F - -doped TiO 2 photocatalyst with anatase and brookite phase was developed by hydrolysis of titanium tetraisopropoxide in a mixed NH 4 F−H 2 O solution. The prepared F - -doped TiO 2 powders were characterized by differential thermal analysis-thermogravimetry (DTA-TG), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV−vis absorption spectroscopy, photoluminescence spectra (PL), transmission electron microscopy (TEM), and BET surface areas. The photocatalytic activity was evaluated by the photocatalytic oxidation of acetone in air. The results showed that the crystallinity of anatase was improved upon F - doping. Moreover, fluoride ions not only suppressed the formation of brookite phase but also prevented phase transition of anatase to rutile. The F - -doped TiO 2 samples exhibited stronger absorption in the UV−visible range with a red shift in the band gap transition. The photocatalytic activity of F - -doped TiO 2 powders prepared by this method exceeded that of Degussa P25 when the molar ratio of NH 4 F to H 2 O was kept in the range of 0.5−3.

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