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A polymer tandem solar cell with 10.6% power conversion efficiency

Jingbi You, Letian Dou, Takehito Kato, Kenichiro Ohya, Tom E. Moriarty, Keith A. Emery, Chun‐Chao Chen, Jing Gao, Gang Li, Yang Yang

Nature Communications · 2013 · 2,781 citationsOpen access

Abstract

An effective way to improve polymer solar cell efficiency is to use a tandem structure, as a broader part of the spectrum of solar radiation is used and the thermalization loss of photon energy is minimized. In the past, the lack of high-performance low-bandgap polymers was the major limiting factor for achieving high-performance tandem solar cell. Here we report the development of a high-performance low bandgap polymer (bandgap <1.4 eV), poly[2,7-(5,5-bis-(3,7-dimethyloctyl)-5H-dithieno[3,2-b:2',3'-d]pyran)-alt-4,7-(5,6-difluoro-2,1,3-benzothia diazole)] with a bandgap of 1.38 eV, high mobility, deep highest occupied molecular orbital. As a result, a single-junction device shows high external quantum efficiency of >60% and spectral response that extends to 900 nm, with a power conversion efficiency of 7.9%. The polymer enables a solution processed tandem solar cell with certified 10.6% power conversion efficiency under standard reporting conditions (25 °C, 1,000 Wm(-2), IEC 60904-3 global), which is the first certified polymer solar cell efficiency over 10%.

Cite this paper

You, J., Dou, L., Yoshimura, K., Kato, T., Ohya, K., Moriarty, T. E., Emery, K. A., Chen, C., Gao, J., Li, G., & Yang, Y. (2013). A polymer tandem solar cell with 10.6% power conversion efficiency. Nature Communications, 4(1), 1446. https://doi.org/10.1038/ncomms2411

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